Catalyst-free synthesis of 2-amino-3-cyanopyridine

2-Amino-3-cyanopyridine

Authors

  • Ibrahim G Mamedov Faculty of Chemistry, Baku State University, Z. Khalilov Str. 23, Az 1148 Baku, Azerbaijan
  • Farid N Naghiyev Faculty of Chemistry, Baku State University, Z. Khalilov Str. 23, Az 1148 Baku, Azerbaijan
  • Victor N Khrustalev Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklay St. 6, Moscow 117198, Russian Federation., ; N. D. Zelinsky Institute of Organic Chemistry RAS, Leninsky Prosp. 47, Moscow 119991, Russian Federation
  • Ekaterina K Kultyshkina Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklay St. 6, Moscow 117198, Russian Federation

DOI:

https://doi.org/10.56042/ijc.v65i5.18162

Keywords:

catalyst-free, cyanopyridine, malononitrile, benzylamine, rearrangement

Abstract

A new compound, 2-amino-4-(4-bromophenyl)-6-(phenylamino)pyridine-3,5-dicarbonitrile, was synthesized by the catalyst-free reaction of 2-(4-bromobenzylidene)malononitrile with malononitrile and benzylamine. The structure of the reaction product was determined by NMR spectroscopy and X-ray diffraction analysis. A probable reaction mechanism and intramolecular rearrangement were proposed.

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Published

2026-06-05

Issue

Vol. 65 No. 5 (2026): Indian Journal of Chemistry-(IJC)

Section

Papers

How to Cite

Catalyst-free synthesis of 2-amino-3-cyanopyridine: 2-Amino-3-cyanopyridine. (2026). Indian Journal of Chemistry (IJC), 65(5), 520-522. https://doi.org/10.56042/ijc.v65i5.18162

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