Synthesis of novel binuclear Cu(II) complex and its application as catalyst for conversion of amine to imine

Authors

DOI:

https://doi.org/10.56042/ijc.v62i11.4504

Abstract

Oxidative coupling reaction of benzylamine to imine has been achieved with almost 90%yield under very mild reaction condition by applying a novel binuclear Cu(II) complex as a catalyst. Binuclear Cu(II) complex, [Cu2(2,3-pydc)1(2,2ꞌ-bpy)4](ClO4)2.2H2O [A] has been synthesised using the ligands 2,3- pyridinedicarboxylic acid (2,3-pydc) and 2,2ꞌ-Bipyridine (2,2ꞌ-bpy). The newly synthesised catalyst has been characterised by using single crystal X-ray diffraction study (SCXRD), UV-Vis spectroscopy, IR-spectroscopy and elemental analysis.

Author Biographies

  • Arunendu Mondal, Department of Chemistry, Central Institute of Technology Kokrajhar (Deemed to be University under MHRD, Govt. of India), Kokrajhar-783370, Assam, India

    Professor

  • Aieshri Swargiary, Department of Chemistry, Central Institute of Technology Kokrajhar (Deemed to be University under MHRD, Govt. of India), Kokrajhar-783370, Assam, India.

    Research Scholar

     

  • Somali Mukherjee, Department of Chemistry, Scottish Church College, 1 & 3 Urquhart Square, Kolkata-700006, India

    Assistant Professor

  • Dulu Brahma, Department of Chemistry, Central Institute of Technology Kokrajhar (Deemed to be University under MHRD, Govt. of India), Kokrajhar-783370, Assam, India

    Research Scholar

  • Pranjal Kalita, Department of Chemistry, Central Institute of Technology Kokrajhar (Deemed to be University under MHRD, Govt. of India), Kokrajhar-783370, Assam, India

    Associate Professor

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Published

2023-11-17

Issue

Vol. 62 No. 11 (2023): Indian Journal of Chemistry-(IJC)

Section

Papers

How to Cite

Synthesis of novel binuclear Cu(II) complex and its application as catalyst for conversion of amine to imine. (2023). Indian Journal of Chemistry (IJC), 62(11), 1186-1192. https://doi.org/10.56042/ijc.v62i11.4504