Plasmonic Enhancement in Bimetallic Ag/Au–GST–BP Multilayer SPR Structures for VOC Detection
DOI:
https://doi.org/10.56042/ijpap.v65i5.28566Keywords:
Surface plasmon resonance sensor, Black phosphorus, Phase-change material, Breath-based biomedical diagnosticsAbstract
This study presents a bimetallic surface plasmon resonance (SPR) sensor for the non-invasive detection of volatile organic compounds (VOCs) in human breath, targeting early diagnosis of liver and pulmonary diseases. The proposed multilayer structure consists of a NaF prism, Ag/Au bilayer, Ge₂Sb₂Te₅ (GST) phase-change material, black phosphorus (BP) layers, and a sensing medium. Finite element simulations using COMSOL Multiphysics were conducted to evaluate angular reflectance characteristics and optimize layer thicknesses and BP stacking. Sensor performance was assessed through resonance angle shifts corresponding to variations in VOC concentration. The optimized configuration, comprising amorphous GST and 18 BP layers, demonstrated superior sensitivity due to enhanced electromagnetic interaction at the sensing interface. The sensor achieved refractive index sensitivities of 1500 RIU⁻¹ for lung disease biomarkers and 163.630 RIU⁻¹ for liver-related biomarkers. These results highlight the potential of the proposed SPR design for accurate, breath-based biomedical diagnostics.
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